主講課程
超分子化學、核燃料循環化學
研究領域及興趣:
超分子化學基礎研究
- 環糊精納米管、環糊精新型包合物、輪烷、分子傳感器等超分子體系的設計合成、結構表征和物化性質研究。
- 超分子光物理、光化學及量熱學研究。
- W/O微乳液、離子液體微乳液的結構特征和基本物化性質研究。
超分子體系在核化學領域的應用基礎研究
- 超分子體系在核燃料化學領域的應用(離子液體、離子印迹聚合物、濁點萃取等核素分離新方法、新技術研究;微乳液在萃取分離體系中的應用研究)。
- 超分子體系中納米粒子的γ-輻射合成及新的調控方法。
代表性論文:
- Fu, J.; Yang, I. Y.; Zhang, J.; Chen, Q. D.; Shen, X. H.*;Gao, Y. Q.* “Structural Characteristics of Homogeneous Hydrophobic Ionic Liquid−HNO3−H2O Ternary System: Experimental Studies and Molecular Dynamics Simulations” J. Phys. Chem. B,2016, DOI: 10.1021/acs.jpcb.6b01214.
- Fu, J.; Chen, Q. D.; Shen X. H.* “Stripping of uranium from an ionic liquid medium by TOPO modified supercritical carbon dioxide” Sci China-Chem2015, 58, 545.
- Shi, J. F.; Shen, X. H.* “Construction of Supramolecular Self-Assemblies Based on the Biamphiphilic Ionic Liquid−β-Cyclodextrin System” J. Phys. Chem. B,2014, 118, 1685.
- Gao, S.; Sun, T. X.; Chen, Q. D.; Shen, X. H.* “Improvement of the Cloud Point Extraction of Uranyl Ions by the Addition of Ionic Liquids” J. Hazard. Mater., 2013, 263, 562.
- Fu, J.; Chen, Q. D.; Sun, T. X; Shen, X. H.* “Extraction of Th(IV) from Aqueous Solution by Room-Temperature Ionic Liquids and Coupled with Supercritical Carbon Dioxide Stripping” Sep. Purif. Technol., 2013, 119, 66.
- Zhang, J. J.; Shen, X. H.* “Temperature-induced reversible transition between vesicle and supramolecular hydrogel in the aqueous ionic liquid-β-cyclodextrin system” J. Phys. Chem. B,2013, 117, 1451.
- Sun, T. X.; Wang, Z. M.; Shen, X. H.* “Crystallization of cesium complex containing bis(2-propyloxy)calix[4]crown-6 and bis[(trifluoromethyl)s, ulfonyl]imide” Inorg. Chim. Acta,2012, 390, 8.
- He, Y. F.; Shen, X. H.*; Chen, Q. D.; Gao, H. C. “Characterization and Mechanism Study of Micrometer-sized Secondary Assembly of β-Cyclodextrin” Phys. Chem. Chem. Phys.2011, 13, 447.
- Chen, Q. D.; Shen, X. H.* “Formation of Mesoporous BaSO4 Microspheres with a Larger Pore Size via Ostwald Ripening at Room Temperature” Cryst. Growth Des.2010, 10, 3838.
- Chen, Q. D.; Shen, X. H.*; Gao, H. C. “Radiolytic Syntheses of Nanoparticles in Supramolecular Assemblies”Adv. Colloid Interface Sci. 2010, 159, 32.
- Xu, C.; Yuan, L. Y.; Shen, X. H.*; Zhai, M. L.* “Efficient removal of caesium ions from aqueous solution using a calix crown ether in ionic liquids: mechanism and radiation effect” Dalton Trans. 2010, 39, 3897.
- Xu, C.; Shen, X. H.*; Chen, Q. D.; Gao, H. C. “Investigation on the extraction of Sr2+ from aqueous phase using crown ether-ionic liquid systems” Sci. China Ser. B-Chem. 2009, 52, 1858.
- He, Y. F.; Chen, Q. D.; Xu, C.; Zhang, J. J.; Shen, X. H.* “Interaction between Ionic Liquids and β-cyclodextrin: A Discussion of Association Pattern” J. Phys. Chem. B.2009, 113, 231.
- He, Y. F.; Fu, P.; Shen, X. H.*; Gao, H. C. “Cyclodextrin-based aggregates” Micron2008, 39, 495. (Invited review article)
- Chen, Q. D.; Shen, X. H.*; Gao, H. C. “Formation of Solid and Hollow Cuprous Oxide Nanocubes in Water-in-oil Microemulsions Controlled by the Yield of Hydrated Electron” J. Colloid Interface Sci.2007, 312, 272.
- Chen, Q. D.; Shen, X. H.*; Gao, H. C. “Formation of Nanoparticles in Water-in-oil Microemulsions Controlled by the Yield of Hydrated Electron. The Controlled Reduction of Cu2+” J. Colloid Interface Sci.2007, 308, 491.
- Wu, A. H.; Shen, X. H.*; Gao, H. C. “Investigation on photophysical properties of a substituted 3H-indole-modified β-cyclodextrin. (II) Efficient photoinduced energy transfer with naphthalene and its derivatives” J. Photochem. Photobiol. A: Chem.2007, 185, 144.
- Wu, A. H.; Chen, Q.; Xia, K.; Hou, T. J.; Shen, X. H.*; Gao, H. C.; Xu, X. J. “Investigation on photophysical properties of a substituted 3H-indole-modified β-cyclodextrin (I) Conformation in water and recognition mechanism as a chemosensor” J. Photochem. Photobiol. A: Chem. 2006, 182, 174.
- Wu, A. H.; Shen, X. H.*; He, Y. K. “Micrometer-sized rodlike structure formed by the secondary assembly of cyclodextrin nanotube” J. Colloid Interface Sci. 2006, 302, 87.
- He, P.; Shen, X. H.*; Gao, H. C. “Size-controlled preparation of Cu2O octahedron nanocrystals and studies on their optical absorption” J. Colloid Interface Sci.2005, 284, 510.
如要了解更多信息,請訪問 超分子化學與材料研究室主頁。
歡迎對本學術組研究工作感興趣的本科生、研究生和博士後加入本學術組。
(2016年6月更新)