張文雄

學術簡曆:

• 2021.01-至今PI，beat365化學學院無機所工作，博雅特聘教授
• 2018.01-2020.12，beat365化學學院有機所工作，博雅特聘教授
• 2016.08-2017.12，beat365化學學院有機所工作，教授
• 2009.10-2009.12，日本理化學研究所客座研究員
• 2007.10-2016.07，beat365化學學院有機所工作，副教授
• 2004.11-2007.09，日本理化學研究所博士後
• 2004.01-2004.03，日本北海道大學JST研究員
• 2002.10-2004.10，beat365化學學院博士後
• 1999.09-2002.09，南開大學化學學院，理學博士
• 1996.09-1999.06，廣西師範大學化學與藥學學院，理學碩士
• 1992.09-1996.07，湖南師範大學化學化工學院，化學教育學士

獲獎情況:

• 2019年獲寶鋼優秀教師獎
• 2019年獲beat365優秀博士學位論文指導教師
• 2017年獲國家傑出青年科學基金
• 2016年獲楊芙清王陽元院士優秀教學科研獎
• 2015年獲Thieme Chemistry Journals Award

科研領域及興趣：

稀土是我國重要的戰略資源，也是不可再生資源。稀土元素因其獨特的4f電子結構和特殊的物理和化學性質，無論從基礎研究還是應用研究的角度都具有重要意義。稀土金屬有機化合物在小分子和惰性化學鍵活化，烯烴聚合，有機合成催化等領域扮演了重要的角色，但反應類型、選擇性和底物範圍同其它過渡金屬有機化合物形成互補。稀土金屬有機雜環化合物，與主族和過渡金屬有機雜環化合物的研究相比，鮮有報道。本課題組的研究思路：建立簡單、高效的合成方法，創建新的稀土金屬有機雜環；結構表征及闡明其成鍵模式，并發現其新的反應性和催化功能；通過反應活性中間體的分離和結構表征，結合計算化學，闡明反應機制；基于發現的新反應，結合國家需求，開發關鍵化學化工産品的新工藝。主要研究興趣包括：

1. 稀土金屬有機雜環化學；
2. 稀土或其它金屬促進的白磷直接合成有機膦的新方法和技術。

代表性論文：

(*: Corresponding author, #: Authors contributed equally)

1. Yu Zheng,# Chang-Su Cao,# Wangyang Ma,# Tianyang Chen, Botao Wu, Chao Yu, Zhe Huang, Jianhao Yin, Han-Shi Hu*, Jun Li, Wen-Xiong Zhang*, and Zhenfeng Xi, 2-Butene Tetraanion Bridged Dinuclear Samarium(III) Complexes via Sm(II)-Mediated Reduction of Electron-Rich Olefins, J. Am. Chem. Soc. 2020,142, 10705-10714.
2. Yang Wang*, Wen-Xiong Zhang*, and Zhenfeng Xi, Carbodiimide-Based Synthesis of N-Heterocycles: Moving from Two Classical Reactive Sites to Chemical Bond Breaking/Forming Reaction, Chem. Soc. Rev. 2020, 49, 5810-5849.
3. Nan Li,# Botao Wu,# Chao Yu, Tianyu Li, Wen-Xiong Zhang*, and Zhenfeng Xi*, Trishomoaromatic (B3N3Ph6) Dianion: Characterization and Two-Electron Reduction, Angew. Chem. Int. Ed. 2020, 59, 8868-8872.
4. Ze-Jie Lv, Zhe Huang, Jinghang Shen, Wen-Xiong Zhang*, and Zhenfeng Xi, Well-Defined Scandacyclopropenes: Synthesis, Structure and Reactivity, J. Am. Chem. Soc. 2019, 141, 20547-20555.
5. Ze-Jie Lv, Zhe Huang, Wen-Xiong Zhang*, and Zhenfeng Xi*, Scandium-Promoted Direct Conversion of Dinitrogen into Hydrazine Derivatives via N-C Bond Formation, J. Am. Chem. Soc. 2019, 141, 8773-8777.
6. Shanshan Du,# Jimin Yang,# Jingyuan Hu, Zhengqi Chai, Gen Luo, Yi Luo, Wen-Xiong Zhang*, and Zhenfeng Xi, Direct Functionalization of White Phosphorus to Cyclotetraphosphanes: Selective Formation of Four P−C Bonds, J. Am. Chem. Soc. 2019, 141, 6843-6847.
7. Jianhao Yin,# Jiapeng Li,# Gao-Xiang Wang,# Zhu-Bao Yin, Wen-Xiong Zhang*, and Zhenfeng Xi*, Dinitrogen Functionalization Affording Chromium Hydrazido Complex, J. Am. Chem. Soc. 2019, 141, 4241-4247.
8. Shanshan Du, Jianhao Yin, Yue Chi, Ling Xu, and Wen-Xiong Zhang*, Dual Functionalization of White Phosphorus: Formation, Characterization, and Reactivity of Rare-Earth-Metal Cyclo-P3 Complexes, Angew. Chem. Int. Ed. 2017, 56, 15886-15890.
9. Baosheng Wei, Liang Liu, Wen-Xiong Zhang*, and Zhenfeng Xi, Synthesis and Structural Characterization of Butadienylcalcium-based Heavy Grignard Reagents and a Ca4[O] Inverse Crown Ether Complex, Angew. Chem. Int. Ed. 2017, 56, 9188-9192.
10. Liang Liu, Miaomiao Zhu, Hai-Tao Yu, Wen-Xiong Zhang*, and Zhenfeng Xi*, Organocopper(III) Spiro Complexes: Synthesis, Structural Characterization, and Redox Transformation, J. Am. Chem. Soc. 2017, 139, 13688-13691.
11. Yongliang Zhang, Junnian Wei, Yue Chi, Xuan Zhang, Wen-Xiong Zhang*, and Zhenfeng Xi*, Spiro Metalla-aromatics of Pd, Pt, Rh: Synthesis and Characterization, J. Am. Chem. Soc. 2017, 139, 5039-5042.
12. Wangyang Ma, Chao Yu, Yue Chi, Tianyang Chen, Lianjun Wang, Jianhao Yin, Baosheng Wei, Ling Xu, Wen-Xiong Zhang*, and Zhenfeng Xi, Formation and Ligand-Based Reductive Chemistry of Bridged Bis-alkylidene Scandium(III) Complexes, Chem. Sci. 2017, 8, 6852-6856.
13. Wangyang Ma,# Chao Yu,# Tianyang Chen,# Ling Xu, Wen-Xiong Zhang*, and Zhenfeng Xi, Metallacyclopentadienes: Synthesis, Structure and Reactivity, Chem. Soc. Rev. 2017, 46, 1160-1192.
14. Liang Liu, Junnian Wei, Yue Chi, Wen-Xiong Zhang*, and Zhenfeng Xi*, Structure and Reaction Chemistry of Magnesium Organocuprates Derived from Magnesiacyclopentadienes and Copper(I) Salts, Angew. Chem. Int. Ed. 2016, 55, 14762-14765.
15. Ling Xu, Yue Chi, Shanshan Du, Wen-Xiong Zhang*, and Zhenfeng Xi, Direct Synthesis of Phospholyl Lithium from White Phosphorus, Angew. Chem. Int. Ed. 2016, 55, 9187-9190.
16. Kunbing Ouyang, Wei Hao, Wen-Xiong Zhang*, and Zhenfeng Xi, Transition-Metal-Catalyzed Cleavage of C–N Single Bonds, Chem. Rev. 2015,115, 12045-12090.
17. Yang Wang, Yue Chi, Wen-Xiong Zhang*, and Zhenfeng Xi*, Regioselective Ring Expansion of 2,4-Diiminoazetidines via Cleavage of C–N and C(sp3)–H bonds: Efficient Construction of 2,3-Dihydropyrimidinesulfonamides, J. Am. Chem. Soc. 2012, 134, 2926-2929.
18. Wen-Xiong Zhang, Shaoguang Zhang, and Zhenfeng Xi*, Zirconocene and Si-Tethered Diynes: A Happy Match Directed towards Organometallic Chemistry and Organic Synthesis, Acc. Chem. Res. 2011, 44, 541-551.
19. Yang Wang, Wen-Xiong Zhang*, Zitao Wang, and Zhenfeng Xi*, Procedure-Controlled Selective Synthesis of 5-Acyl-2-iminothiazolines and their Selenium and Tellurium Derivatives by Convergent Tandem Annulation, Angew. Chem. Int. Ed.2011, 50, 8122-8126.
20. Zitao Wang, Yang Wang, Wen-Xiong Zhang*, Zhaomin Hou, and Zhenfeng Xi*, Efficient One-Pot Synthesis of 2,3-Dihydropyrimidinthiones via Multicomponent Coupling of Terminal Alkynes, Elemental Sulfur, and Carbodiimides, J. Am. Chem. Soc. 2009, 131, 15108-15109.