張 文 雄 博士,教授,博士生導師 研究方向:配位化學、稀土金屬有機化學和元素有機化學 辦公室:化學樓A630 辦公室電話:010-6275-8294 電子信箱:wx_zhang@pku.edu.cn 教育和工作經曆: 2021.01-至今 PI,beat365化學學院無機所工作,博雅特聘教授 2018.01-2020.12,beat365化學學院有機所工作,博雅特聘教授 2016.08-2017.12,beat365化學學院有機所工作,教授 2009.10-2009.12,日本理化學研究所客座研究員 2007.10-2016.07,beat365化學學院有機所工作,副教授 2004.11-2007.09,日本理化學研究所博士後 2004.01-2004.03,日本北海道大學JST研究員 2002.10-2004.10,beat365化學學院博士後 1999.09-2002.09,南開大學化學學院,理學博士 1996.09-1999.06,廣西師範大學化學與藥學學院,理學碩士 1992.09-1996.07,湖南師範大學化學化工學院,化學教育學士 部分榮譽及獎勵:
2024年獲國家自然科學獎二等獎(2/5) 2024年獲首屆“武創源”國際光化學及綠色制造技術創新大賽創新引領獎 2019年獲寶鋼優秀教師獎 2019年獲beat365優秀博士學位論文指導教師 2017年獲國家傑出青年科學基金 2016年獲楊芙清王陽元院士優秀教學科研獎 2015年獲Thieme Chemistry Journals Award 部分社會服務與學術兼職: 2023- Organometallics, Member of Editorial Advisory Board 2019- Green Synthesis & Catalysis (Elsevier B. V.) 副主編 2019- Chinese Chemical Letters (CCL) 編委 2019- Chemical Research in Chinese Universities 青年編委 2018- Chinese Journal of Organic Chemistry 編委 2017- Chinese Journal of Chemistry 青年編委 2024- 武漢工程大學客座教授 2024- 湘潭大學環境友好化學與應用教育部重點實驗室學術委員會委員 2024- 江西理工大學離子型稀土資源開發及應用教育部重點實驗室會議學術委員會委員 2023- 中國化學會磷化學專業委員會副主任委員 2023- 中國化學會第三十一屆理事會有機化學學科委員會委員 2023- 湖南師範大學化學生物學及中藥分析教育部重點實驗室學術委員會委員 2020- 中國化學會高級會員 2020- 中國稀土學會稀土分子材料與超分子器件專業委員會委員 2019- 北京化學會第十八屆理事會理事 2018- 衡陽師範學院客座教授 2017- 湖北大學有機功能分子合成與應用教育部重點實驗室學術委員會委員 2017- 廣西師範大學客座教授 2016- 中國晶體學會第一屆監事會監事
代表性論文:
(*: Corresponding author, #: Authors contributed equally)
1. Yu Zheng#, Chang-Su Cao#, Wangyang Ma#, Tianyang Chen, Botao Wu, Chao Yu, Zhe Huang, Jianhao Yin, Han-Shi Hu*, Jun Li, Wen-Xiong Zhang*, and Zhenfeng Xi, 2-Butene Tetraanion Bridged Dinuclear Samarium(III) Complexes via Sm(II)-Mediated Reduction of Electron-Rich Olefins,
J. Am. Chem. Soc. 2020, 142, 10705-10714.
2. Yang Wang*, Wen-Xiong Zhang*, and Zhenfeng Xi, Carbodiimide-Based Synthesis of N-Heterocycles: Moving from Two Classical Reactive Sites to Chemical Bond Breaking/Forming Reaction,
Chem. Soc. Rev. 2020, 49, 5810-5849.
3. Nan Li#, Botao Wu#, Chao Yu, Tianyu Li, Wen-Xiong Zhang*, and Zhenfeng Xi*, Trishomoaromatic (B3N3Ph6) Dianion: Characterization and Two-Electron Reduction,
Angew. Chem. Int. Ed. 2020, 59, 8868-8872.
4. Ze-Jie Lv, Zhe Huang, Jinghang Shen, Wen-Xiong Zhang*, and Zhenfeng Xi, Well-Defined Scandacyclopropenes: Synthesis, Structure and Reactivity,
J. Am. Chem. Soc. 2019, 141, 20547-20555.
5. Ze-Jie Lv, Zhe Huang, Wen-Xiong Zhang*, and Zhenfeng Xi*, Scandium-Promoted Direct Conversion of Dinitrogen into Hydrazine Derivatives via N-C Bond Formation,
J. Am. Chem. Soc. 2019, 141, 8773-8777.
6. Shanshan Du#, Jimin Yang#, Jingyuan Hu, Zhengqi Chai, Gen Luo, Yi Luo, Wen-Xiong Zhang*, and Zhenfeng Xi, Direct Functionalization of White Phosphorus to Cyclotetraphosphanes: Selective Formation of Four P−C Bonds,
J. Am. Chem. Soc. 2019, 141, 6843-6847.
7. Jianhao Yin#, Jiapeng Li#, Gao-Xiang Wang#, Zhu-Bao Yin, Wen-Xiong Zhang*, and Zhenfeng Xi*, Dinitrogen Functionalization Affording Chromium Hydrazido Complex,
J. Am. Chem. Soc. 2019, 141, 4241-4247.
8. Shanshan Du, Jianhao Yin, Yue Chi, Ling Xu, and Wen-Xiong Zhang*, Dual Functionalization of White Phosphorus: Formation, Characterization, and Reactivity of Rare-Earth-Metal Cyclo-P3 Complexes,
Angew. Chem. Int. Ed. 2017, 56, 15886-15890.
9. Baosheng Wei, Liang Liu, Wen-Xiong Zhang*, and Zhenfeng Xi, Synthesis and Structural Characterization of Butadienylcalcium-based Heavy Grignard Reagents and a Ca4[O] Inverse Crown Ether Complex,
Angew. Chem. Int. Ed. 2017, 56, 9188-9192.
10. Liang Liu, Miaomiao Zhu, Hai-Tao Yu, Wen-Xiong Zhang*, and Zhenfeng Xi*, Organocopper(III) Spiro Complexes: Synthesis, Structural Characterization, and Redox Transformation,
J. Am. Chem. Soc. 2017, 139, 13688-13691.
11. Yongliang Zhang, Junnian Wei, Yue Chi, Xuan Zhang, Wen-Xiong Zhang*, and Zhenfeng Xi*, Spiro Metalla-aromatics of Pd, Pt, Rh: Synthesis and Characterization,
J. Am. Chem. Soc. 2017, 139, 5039-5042.
12. Wangyang Ma, Chao Yu, Yue Chi, Tianyang Chen, Lianjun Wang, Jianhao Yin, Baosheng Wei, Ling Xu, Wen-Xiong Zhang*, and Zhenfeng Xi, Formation and Ligand-Based Reductive Chemistry of Bridged Bis-alkylidene Scandium(III) Complexes,
Chem. Sci. 2017, 8, 6852-6856.
13. Wangyang Ma#, Chao Yu#, Tianyang Chen#, Ling Xu, Wen-Xiong Zhang*, and Zhenfeng Xi, Metallacyclopentadienes: Synthesis, Structure and Reactivity,
Chem. Soc. Rev. 2017, 46, 1160-1192.
14. Liang Liu, Junnian Wei, Yue Chi, Wen-Xiong Zhang*, and Zhenfeng Xi*, Structure and Reaction Chemistry of Magnesium Organocuprates Derived from Magnesiacyclopentadienes and Copper(I) Salts,
Angew. Chem. Int. Ed. 2016, 55, 14762-14765.
15. Ling Xu, Yue Chi, Shanshan Du, Wen-Xiong Zhang*, and Zhenfeng Xi, Direct Synthesis of Phospholyl Lithium from White Phosphorus,
Angew. Chem. Int. Ed. 2016, 55, 9187-9190.
16. Kunbing Ouyang, Wei Hao, Wen-Xiong Zhang*, and Zhenfeng Xi, Transition-Metal-Catalyzed Cleavage of C–N Single Bonds,
Chem. Rev. 2015, 115, 12045-12090.
17. Yang Wang, Yue Chi, Wen-Xiong Zhang*, and Zhenfeng Xi*, Regioselective Ring Expansion of 2,4-Diiminoazetidines via Cleavage of C–N and C(sp3)–H bonds: Efficient Construction of 2,3-Dihydropyrimidinesulfonamides,
J. Am. Chem. Soc. 2012, 134, 2926-2929.
18. Wen-Xiong Zhang, Shaoguang Zhang, and Zhenfeng Xi*, Zirconocene and Si-Tethered Diynes: A Happy Match Directed towards Organometallic Chemistry and Organic Synthesis,
Acc. Chem. Res. 2011, 44, 541-551.
19. Yang Wang, Wen-Xiong Zhang*, Zitao Wang, and Zhenfeng Xi*, Procedure-Controlled Selective Synthesis of 5-Acyl-2-iminothiazolines and their Selenium and Tellurium Derivatives by Convergent Tandem Annulation,
Angew. Chem. Int. Ed. 2011, 50, 8122-8126.
20. Zitao Wang, Yang Wang, Wen-Xiong Zhang*, Zhaomin Hou, and Zhenfeng Xi*, Efficient One-Pot Synthesis of 2,3-Dihydropyrimidinthiones via Multicomponent Coupling of Terminal Alkynes, Elemental Sulfur, and Carbodiimides,
J. Am. Chem. Soc. 2009, 131, 15108-15109.