張文雄2007年10月從日本理化學研究所回到beat365化學與分子工程學院有機所工作，任副教授，在席振峰院士課題組開展科研工作，2016年晉升為教授，2017年獲得國家傑出青年科學基金。通過國際評估等程序，2021年1月始，在beat365beat365無機所建立“稀土金屬有機化學”課題組（英文名稱：Chemistry of Carbon˗Rare Earth Metals，簡稱：CCREM課題組），任課題組長/PI。CCREM課題組秉承“CCREM (Confidence/自信、Cooperation/協同、Renovation/創新、Enthusiasm/激情、Mission/擔當)”文化和協同管理理念。本課題組圍繞高活性稀土金屬有機雜環的合成、結構表征、成鍵模式及對小分子的活化和反應機理開展系列研究：首次實現了稀土金屬雜環戊二烯、高張力稀土金屬雜環丙烯和雙钐雜環戊烯的高效合成；實現了稀土金屬有機雜環或雙金屬試劑促進的從白磷出發直接構建有機膦化合物；發現了首例稀土金屬休克爾芳香性化合物等。在此工作基礎上，拟開展：1）避開傳統的氯化路線，建立簡單、高效的白磷活化方法直接構建有機膦化合物；2）新的稀土金屬有機雜環的合成，并研究與小分子，如白磷，CO，CO2，氧氣等的反應性和催化活性。

現課題組誠聘博士後研究人員1-4名，科研助理1-4名，要求在有機合成化學、金屬有機化學、或過渡金屬配位化學、或光化學、或電化學、或磁分子材料化學等研究領域有較好的工作積累。集中開展白磷的選擇性斷鍵直接構建有機膦化合物或稀土金屬有機雜環的合成及功能研究。

提供有競争力的薪酬，具體待遇等請聯系：張文雄教授，電話：010-62758294，電子信箱：wx_zhang@pku.edu.cn，課題組網頁：/zhangwx/。

代表性論文：

(*: Corresponding author, #: Authors contributed equally)

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2. Yu Zheng,# Chang-Su Cao,# Wangyang Ma,# Tianyang Chen, Botao Wu, Chao Yu, Zhe Huang, Jianhao Yin, Han-Shi Hu*, Jun Li, Wen-Xiong Zhang*, and Zhenfeng Xi, 2-Butene Tetraanion Bridged Dinuclear Samarium(III) Complexes via Sm(II)-Mediated Reduction of Electron-Rich Olefins, J. Am. Chem. Soc. 2020, 142, 10705-10714.
3. Nan Li,# Botao Wu,# Chao Yu, Tianyu Li, Wen-Xiong Zhang*, and Zhenfeng Xi*, Trishomoaromatic (B3N3Ph6) Dianion: Characterization and Two-Electron Reduction, Angew. Chem. Int. Ed. 2020, 59, 8868-8872.
4. Ze-Jie Lv, Zhe Huang, Jinghang Shen, Wen-Xiong Zhang*, and Zhenfeng Xi, Well-Defined Scandacyclopropenes: Synthesis, Structure and Reactivity, J. Am. Chem. Soc. 2019, 141, 20547-20555.
5. Ze-Jie Lv, Zhe Huang, Wen-Xiong Zhang*, and Zhenfeng Xi*, Scandium-Promoted Direct Conversion of Dinitrogen into Hydrazine Derivatives via N-C Bond Formation, J. Am. Chem. Soc. 2019, 141, 8773-8777.
6. Shanshan Du,# Jimin Yang,# Jingyuan Hu, Zhengqi Chai, Gen Luo, Yi Luo, Wen-Xiong Zhang*, and Zhenfeng Xi, Direct Functionalization of White Phosphorus to Cyclotetraphosphanes: Selective Formation of Four P−C Bonds, J. Am. Chem. Soc. 2019, 141, 6843-6847.
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8. Wangyang Ma, Chao Yu, Yue Chi, Tianyang Chen, Lianjun Wang, Jianhao Yin, Baosheng Wei, Ling Xu, Wen-Xiong Zhang*, and Zhenfeng Xi, Formation and Ligand-Based Reductive Chemistry of Bridged Bis-alkylidene Scandium(III) Complexes, Chem. Sci. 2017, 8, 6852-6856.
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10. Ling Xu, Yue Chi, Shanshan Du, Wen-Xiong Zhang*, and Zhenfeng Xi, Direct Synthesis of Phospholyl Lithium from White Phosphorus, Angew. Chem. Int. Ed. 2016, 55, 9187-9190.