beat365官方网站張文雄課題組誠聘博士後研究人員_招聘信息

張文雄2007年10月從日本理化學研究所回到beat365化學與分子工程學院有機所工作，任副教授，在席振峰院士課題組開展科研工作，2016年晉升為教授，2017年獲得國家傑出青年科學基金。通過國際評估等程序，2021年1月始，在beat365化學與分子工程學院無機所建立“稀土金屬有機化學”課題組，任課題組長/PI。本課題組圍繞高活性稀土金屬有機雜環化合物的合成、結構表征、成鍵模式及對小分子的活化和反應機理開展系列研究：首次實現了稀土金屬雜環戊二烯的高效合成，在此基礎上首次實現了從白磷出發直接構建有機膦化合物，為稀土金屬及白磷的高效利用提供了新思路；首次實現了高張力稀土金屬雜環丙烯的合成和結構表征，發現其具有休克爾芳香性；成功構建了雙钐雜環戊烯，首次實現了雙碳負離子型共轭烯烴的還原，揭示該雙碳負離子的反鍵軌道能夠從能量更高的钐4f軌道接收兩個電子。在已有工作基礎上，拟開展：1）新的稀土金屬有機雜環的合成，并研究與小分子，如白磷，CO，CO2，氧氣等的反應性和催化活性；探索芳香性稀土金屬有機雜環的合成和成鍵模式；2）利用金屬有機化學手段，建立簡單、高效的白磷活化方法直接構建有機膦化合物，打破傳統的工業路線，實現白磷的直接應用。

現課題組誠聘博士後研究人員1-4名，要求在金屬有機化學、或過渡金屬配位化學、或光化學、或電化學研究領域有較好的工作積累，進站後開展稀土金屬有機雜環化學或白磷的轉化化學研究。

具體待遇等請聯系：張文雄教授 /ktz2/wjhxktzz/125454.htm，電話：010-62758294，電子信箱：wx_zhang@pku.edu.cn

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(*: Corresponding author, #: Authors contributed equally)

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